Dr.
Joel Wallach, BS, DVM, ND |
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COLLOIDAL MINERALS Colloidal (Kol-oid-al) chemistry is not new, but it is not widely known about or understood by the general public. Simply said, a colloid refers to a substance that exists as ultra-fine particles that are suspended in a medium of different matter. The colloidal state is the state of a solute (mineral or other substance such as a paint pigment) in a solution when its molecules do not separate into atoms as with a true solution (sodium chloride or salt separates into separate sodium and chloride atoms while in solution), but rather they remain grouped together to form solute particles. The presence of these inorganic colloidal particles, which are approximately one hundred-thousandth to one ten-millionth of a centimeter in diameter (about 400 thousandths to four millionths of an inch), can often be detected by means of an electron microscope. As a result of the grouping of the molecules, a solute in the colloidal state cannot pass through a suitable semi permeable membrane and gives rise to negligible osmotic pressure (they will pass through filter paper), depression of freezing point and elevation of boiling point effects. These ultra-fine particles of the colloid are just barely larger than most molecules and so small they can't be seen with the naked eye - about one billion of these colloid particles would fit into a cubic 0.01 of an inch. The "solution" part of a colloid provides a solid, gas or liquid medium in which the colloid particles are suspended. The suspended particles in a colloid can also be a solid, a gas or a liquid Solutions were classified by H Freundlich (1925) into three categories:
The four part method of classifying solutions is as follows:
In 1975, S. S. Voyutsky (a Russian) wrote the classic text on colloidal chemistry. Voyutsky referred to solutions as "molecular dispersion systems" and "heterogeneous highly dispersed colloidal systems." The exact point between the molecular and colloidal degrees of dispersion cannot be established because the transition from molecularly dispersed systems to coarsely dispersed systems is a continuous range. A colloidal system must have three basic characteristics:
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Inorganic colloidal material which readily passes through filter paper may be separated from dissolved substances, such as starch, sugar or salt, by placing the mixture of mineral colloid and non colloid in a parchment shell surrounded by distilled water. The inorganic colloids are "too large" to pass through the membrane, but the molecules of salt, starch and sugar or any other dissolved substance pass readily through the semi permeable membrane (they separate into individual atoms or very small molecules). This kind of separation process is called dialysis. In the process of digestion the inorganic minerals in food or supplements soon become inorganic colloids and as an inorganic colloid they cannot penetrate the intestinal wall to enter the blood stream. In the presence of amino acids a small percentage of the inorganic colloids form Chelated minerals and organic colloids which are able to be dialyzed through the mucus membranes of the intestinal walls into the blood stream - this form of bio available mineral state is known as a "crystalloid." Crystalloids or organic colloids readily pass through cell walls, while non-organic colloids are "too large." Additionally we must remember that in the living organism there are other physiological forces at work which interfere with or modify the expected osmotic phenomenon.
Colloidal mineral supplements and commercial colloids are
found in four different forms:
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